The persistent radical effect in controlled radical polymerizations

Kinetic Gelation Modeling of Controlled Radical Polymerizations

A kinetic gelation model has been developed that incorporates the kinetics of a living/ controlled radical polymerization. Specifically, the kinetics of an iniferter polymerization were implemented in the model to determine the effect of the kinetics on the polymer structure. In particular, the replacement of the termination step with a reversible termination was examined. The model predicts th...

Chapter I: Controlled/”living” Free Radical Polymerizations

Radical-Mediated Enzymatic Polymerizations

Polymerization reactions are commonly effected by exposing monomer formulations to some initiation stimulus such as elevated temperature, light, or a chemical reactant. Increasingly, these polymerization reactions are mediated by enzymes--catalytic proteins--owing to their reaction efficiency under mild conditions as well as their environmental friendliness. The utilization of enzymes, particul...

Enzyme Initiated Radical Polymerizations

Biocatalysis is propagating into practically every area of organic chemistry, amongst them radical polymerizations. A review of the recent developments of this dynamic and quickly evolving area of research is presented together with a critical evaluation of its potential to yield novel polymers and/or environmentally more benign synthetic procedures.

Various radical polymerizations of glycerol-based monomers